WCF Architecture Overview –
http://msdn.microsoft.com/en-us/library/aa480210.aspx
WCF Getting Started –
http://msdn.microsoft.com/en-us/library/ms734712.aspx
WCF 3.5 samples –
http://msdn.microsoft.com/en-us/library/ms751514.aspx
WCF 4.0 samples –
http://msdn.microsoft.com/library/dd483346(VS.100).aspx
Net endpoint blog (Blog by the .NET and AppFabric teams about WCF and WF development, deployment, and management) –
http://blogs.msdn.com/endpoint/
WCF REST Starter Kit –
http://www.asp.net/downloads/starter-kits/wcf-rest
WCF Forum –
http://social.msdn.microsoft.com/Forums/en/wcf/threads/
WCF Test Client – (WcfTestClient.exe)
http://msdn.microsoft.com/en-us/library/bb552364.aspx